WWTP2GREENFUELS PROPOSAL

WWTP2 GREENFUELS PROPOSAL

Bioenergy is considered a key source to meet EU 2020 energetic targets such as GHGs emission reduction, energy security and economic growth. It can contribute to replace fossil fuels in all energy markets. Other renewable sources, such as solar and wind, can easily be applied to produce heat and electricity but they show strong intermittent loads. Therefore, bioenergy will be more promoted to produce intermediate energy carriers such as renewable biomethane and green H₂, which can be utilized on demand and therefore provide flexibility to the energy system. Moreover, the utilization of bioenergy shall be promoted to replace fossil fuels, especially coke, in the process industries such as the metallurgy, cement, aluminum or paper and pulping. These industry sectors release around 21% of GHGs emissions. Therefore, intermediate bioenergy carries such as biomethane and green hydrogen for process industry application would be much appreciated.

Renewable biomethane can be used as intermediate energy carrier for gas-grid injection pathway to balance the power grid and to increase the flexibility of the energy system. On the other hand, biomethane generated from the wastewater plant, as it is proposed in this project, can be used as a fuel or raw material for the steel industry or can be also upgraded to produce green hydrogen by different reforming strategies. The development of efficient catalytic formulations for the dry-, steam- , and bi-reforming of biogas will allow to develop new industrial technologies to produce green hydrogen at large scale.

The main objective of this project is

to investigate and develop innovative approaches to produce bioenergy

(Biomethane and green hydrogen) from lowquality biogenic feedstock produced by a wastewater plant

the preparation and application of novel catalysts

for dry and steam reforming based on structured metals and transition metal oxides supported on anionic clays, perovskites and other low cost and recyclable supports

Contribute to the UN sustainability goals

● Affordable and clean energy, ● Decent work and economic growth, ● Industrial, innovation and infrastructure, ● Sustainable consumption and production and ● Climate changes.

The main aim of this project is to study in a microplant scale the anaerobic codigestion to produce a methane enriched biogas with lower hydrogen sulfide and nitrogen compounds contents, the conversion of biogas into natural gas (biomethane) and the production of green hydrogen by dry and steam reforming and bireforming, and its further purification by water gas shift reaction combined with CO₂ capture. The proposal includes the preparation of novel catalysts for dry and steam reforming based on structured metals and transition metal oxides supported on anionic clays, perovskites and other low cost and recyclable supports (i.e., shell eggs), and the corresponding purification processes to attain high purity biomethane or green hydrogen apt as biofuels with low contents of hydrogen sulfide, water, and siloxanes and without CO₂ emission. The proposed catalysts will be compared with commercial ones, and all the processes will be modeled to define the best option for its application in a WWTP.

With experience in the field of adsorption and catalysis

Sinergetic skills of the groups and subprojects

The project is very ambitious, covering different aspects, and will be executed by two different groups, specialized each one in specific tasks. While each subproject can stand alone, some targets have interrelated aspects among the groups, which will allow them to proceed in a more efficient way than that achieved by working separately, sharing the knowledge and research facilities of the groups.

subproject 1

Biomethane and Hydrogen
Production and Purification from
an Anaerobic Digester.

CO₂, H₂S and NH₃ capture
Gas separation
Surface Analysis
Adsorbents preparation
Codigestion
Multiphysics Modeling

IP 1: Enrique Rodriguez Castellón
IP 2: Juan Manuel Paz García

subproject 2

Innovative Catalytic Formulations for Dry Reforming and WGS Reactions and their Impact in the Sustainable Production of Green Hydrogen from Biogas

Thermocatalytic valorization of CO₂
Thermocatalytic ODH of ethane and CO₂
Hydroformilation of olefins with CO₂
Operando characterization
In-situ tests

IP 1: José Manuel López Nieto
IP 2: Patricia Concepción Heydorn

The University of Malaga (UMA)

The University of Malaga (UMA), with a group consisting of the joint participation of Chemists, Chemical Engineers and Biologists, of the Departments of Inorganic Chemistry, Chemical Engineering and Microbiology, with vast experience in Catalysis, Separation and Codigestion. In addition, three foreign collaborators from Universidade Federal do Ceará (Brasil) and University of Bologna (Italy) with experience in Adsorption and Catalysis participate in the UMA group.

The combined group of the University of Malaga (UMA) has a long experience in the preparation of mesoporous and structured materials with application as adsorbents of toxic gases, such as H₂S and CO₂, surface characterization and catalytic processes, and on the co-digestion processes including modeling and environmental and engineering studies.

The Institute of Chemical Technology of Valencia (ITQ)

The Institute of Chemical Technology (ITQ) is a joint research center created in 1990 by the Universitat Politècnica de València (UPV) and the Consejo Superior de Investigaciones Científicas (CSIC) located at the UPV Campus. The ITQ is a reference center in catalysis, new materials (especially zeolites) and photochemistry. Thanks to its excellent level of fundamental and oriented research and its multidisciplinary nature, the ITQ can act at interfaces between disciplines, thus having broad flexibility and rapid adaptation to new lines and challenges. It has specialized human resources, as well as state-of-the-art facilities to carry out research in the field of chemical technologies and new materials. It is made up of more than two hundred professionals from all over the world divided into, Research Professors, Researchers and tenured Scientists of the CSIC, invited Professors, senior technicians, administrative and support staff, as well as scholarship holders and contractors pre- and post-doctoral studies.

The group of the ITQ, has extensive experience in the synthesis of advanced materials with proper control of active sites to be used as catalysts for chemicals production and proved knowledge in in-situ and operando spectroscopic studies. The group has been involved in catalysts development for many catalytic processes, such as steam reforming of methanol and ethanol, and activation of low weight alkanes by acid and redox processes, among others.

OUR TEAM

Our research team is made up of the following professors and researchers:

Members of the University of Malaga team gathered

UMA - Research group

Name	Acronym
Enrique Rodríguez Castellón	ERC
José Jiménez Jiménez	JJJ
Juan Antonio Cecilia Buenestado	JACB
María Olga Guerrero Pérez	MOGP
Juan Manuel Paz García	JMPG
José Miguel Rodríguez Maroto	JMRM
César Gómez Lahoz	CGL
Carlos Vereda Alonso	CVA

UMA - Working group

Name	Acronym
M.V. Martínez de Yuso García	MVMY
Ana Arango Díaz	AAD
María Dolores Márques	jygjyg
Patricia Benito Martín	PBM
Alcineia Oliveira	AO
María Villén Guzmán	MVG
Elena Rodríguez Aguado	ERA
Ana Lucena Serrano	ALS
Daniel Ballesteros Plata	DBP
Diana C.S. Azevedo	DCA
Silvana Tapia Paniagua	STP
Isabel Barroso Martín	IBM
Brahim Arhoun	BA
María M. Cerrillo González	MMCG
Postdoctoral Contract 1	PC1
Postdoctoral Contract 2	PC2

ITQ laboratory

ITQ - Research group

Name	Acronym
José Manuel López Nieto	JMLN
Patricia Concepción Heydorn	PCH
Marcelo E. Domine Maccari	MED

ITQ - Working group

Name	Acronym
Marisa B. Navas	MVN
José Soriano Rodríguez	JSR
Mª Dolores Soriano Rodríguez	MDS
Carmen Tebar Soler	CTS
Adelina Muñoz Algaba	AMA
Technician Contract (required)	TC1
Technician Contract (required)	TC2

State-of-the-art of Green biomethane and hydrogen production

The anaerobic digestion process in a wastewater treatment plant (WWTP) is a complex process with several organic matter degradation steps:

The Hydrolysis of the organic matter converts it into soluble organic compounds;
Acidogenesis transforms these compounds to intermediates materials (volatile fatty acids and alcohols);
Acetogenesis mainly produces acetate, carbon dioxide and hydrogen;
and finally, in the Methanogenesis process, acetate is oxidized into biogas (a mixture of CH₄ and CO₂ in approximately 3:2 proportion, with traces of impurities such as water, carbon monoxide, hydrogen sulfide, ammonia, nitrogen and siloxanes)

The use of biogas to produce green hydrogen is a mature technology in some aspects.

The most common hydrogen production methods using biogas as primary source are:

I. a biogas-to-hydrogen plant through steam reforming (SR); and

II. a biogas-to-hydrogen plant through autothermal reforming (ATR).

Figure 2: Configurations of a biogas-to-hydrogen plant based on the steam reforming process (B2H_SR), based on the autothermal reforming process (B2H_ATR) and based on dry reforming process (B2H_DR).

A newer and innovative option is dry reforming (DR) for obtaining syngas (CO + H₂), which can be after, by water gas shift reaction, transformed to pure hydrogen or directly used in a high temperature fuel cell (SOFC) to produce electricity and heat. The plants using the SR, ATR and DR are able to produce high-pressure hydrogen, heat, and electricity for self-sustaining the energy consumption for purification, compression, and storage of the produced hydrogen. These plants are proposed as on-site hydrogen production plants for the development of novel refueling stations (see Figure 2).

The steam reforming-based configuration show the best performance in terms of hydrogen production energy-based efficiency and hydrogen production energy-based efficiency. Moreover, it represents the best solution also considering the co-production of heat and hydrogen, while the autothermal reforming process layout is more exothermic and can be indicated when a larger local heat demand exists.

On the other hand, dry reforming is an innovative route to avoid the emission of CO₂ since implies the reaction of CO₂ with CH₄ to produce H₂. In the three processes, the incorporation of a Water Gas Shift unit is obliged to purify hydrogen for its use in low temperature fuel cell (i.e., PEM fuel cell). On the other hand, steam reforming and autothermal reforming are the two major techniques for conversion of CH₄ in biogas to H₂ and CO, and dry reforming for conversion of CH₄ and CO₂ in biogas to H₂ and CO, which then can be used for the production of liquid fuels or used directly in a high temperature fuel-cells (SOFC).

Given that biogas consists of a mixture of CH₄, H₂O and CO2, upgrading biogas into H2 and CO (syngas) without further CO₂ separation by dry/steam reforming can be a viable option. It is important to note that dry reforming offers an environmentally-friendly way to convert CO₂ into combustible gas (CO). Steam reforming process requires pressurized steam (3–20 bar) to expedite the conversion of 8 de 35 CH₄ into syngas, while dry reforming occurs at atmospheric pressure. Thus, dry reforming available at atmospheric pressure enables an integration of biogas and dry reforming process with no installation of complicated facilities to connect atmospheric pressure biogas plant and dry reforming reactor.

Figure 3: Green hydrogen production by dry reforming connected to a WGS unit where a bifunctional catalyst is used to produce a high purity H₂ (green hydrogen) and CO₂. CO₂ can be used again in the dry reforming unit.

In addition, another important novelty will be introduced with the application of an additional hydrogen purification unit based on sorption enhanced water gas shift reaction. Bifunctional catalysts will be used in this unit in order to produce highly pure green hydrogen stream via simultaneous capturing and sequestration of the CO₂ produced in the WGS process. In this process, the captured CO₂ will be released during a second catalyst regeneration step and recycled in the dry reforming unit avoiding its emission to the atmosphere (Figure 3). In this direction, catalyst stability and lifetime are important aspects to be considered.

As indicated above, the presence of water in the gaseous mixture, together with methane and CO₂, would allow the combined use of dry and steam reforming, in the so-called “bi-reforming”. Indeed, steam reforming of methane is currently, together with water electrolysis, the most economical and widely used method for obtaining hydrogen. Similarly to the dry reforming, this process can be represented by steam reforming (endothermic), water-gas shift (exothermic) and CH₄ + ₂H₂O = CO₂ + ₄H₂, endothermic. Since dry reforming generally increases the tendency for coke formation, the addition of H₂O to the reactive mixture can improve the stability of the catalytic systems.

References

– https://www.epa.gov/ghgemissions/global-greenhouse-gas-emissions-data.
– M. Minutillo, A. Perna, A. Sorce, Appl. Energie 277 (2020) 115452.
– F.M. Baena-Moreno, D. Sebastia-Saez, L. Pastor-Pérez, T. Ramirez Reina, Renewable and Sustainable Energy Reviews 144 (2021) 110939.
– B. Teichgräber, A. Kraft, D. Rossol, M. Schröder, Green Hydrogen and Natural Gas from Digester Gas of Wastewater Treatment Plants, Proceedings of the WHEC, May 16.-21. 2010, Essen. ISBN: 978-3-89336-653-8.
– M. Reinders, P. Beckhaus, F. Illing, U. Misz , H. Riße, M. Schröder, P. Schulte, B. Teichgräber,
International Journal of Hydrogen Energy 40 (2015) 8601.
– M.J. Park, J.H Kim, Y.H. Lee, H.M. Kim, D.W. Jeong, Int. J. of Hydrogen Energy 45 (2020) 30188.
– R. García, M.V. Gil, F. Rubiera, D. Chen, C. Pevida, Energy 218(2021) 119491.
– F.M. Baena-Moreno, L. Pastor-Pérez, Q. Wang, T.R. Reina. J. Cleaner Production 265 (2020) 121909.
– L.N. Nguyen, J. Kumar, M.T. Vu, J.A.H. Mohammed, Nirenkumar Pathak, A.S. Commault, D. Sutherland, J. Zdarta, V. Kumar-Tyagi, L.D. Nghiem, Science of the Total Environment 765 (2021) 142753.
– M. Schäfer, O. Gretzschel, H. Steinmetz, Energies 13 (2020) 2088.
– S.E. Hosseini, Energy Conversion and Management 211 (2020) 112760.
– S.A. Chattanathan, S. Adhikari, M. McVey, O. Fasina, Int. J. Hydrogen Energy 39 (2014) 19905.
– P. Tarifa, N. Schiaroli, P.H. Ho, F. Cañaza, F. Ospitali, G. Sanghez de Luna, C. Lucarelli, G. Fornasari, A. Vaccari, A. Monzon, P. Benito, Catal. Today 2022 (383) 74.
– S. Jung, J. Lee, D.H. Moon, K.H. Kim, E.E. Kwon, Renewable and Sustainable Energy Reviews 143 (2021) 110949.
– E. Finocchio, T. Montanari, G. Garuti, C. Pistarino, F. Federici, M. Cugino, G. Busca, Energy Fuels 23 (2009) 4156–4159.
– P. Tu, D.N. Le, T.D. Dao, Q-T. Tran , T.C.D. Doan, Y. Shiratori, et al. Int. J. Hydrogen Energy. 45 (2020) 18363.
– Charisiou ND, Iordanidis A, Polychronopoulou K, Yentekakis IV, Goula MA. Materials Today:
Proceedings. 5 (2018) 27607-16.
– M.A. Goula, N.D. Charisiou, G. Siakavelas L. Tzounis, I. Tsiaoussis, P. Panagiotopoulou P, et al. Int. J. Hydrogen Energy. 42 (2017) 13724.
– T.G.H. Nguyen, D.L. Tran, M. Sakamoto, T. Uchida, K. Sasaki, T.D., et al. Int. J. Hydrogen Energy. 43 (2018) 4951.
– J.J. González-Pérez, J.F. Da Costa-Serra, A. Chica. Int. J. Hydrogen Energy. 45 (2020) 20568-20581.
– V.M. González-DelaCruz, J.P. Holgado, R. Pereñíguez, A. Caballero, J. Catal., 257 (2008) 307.
– A. Caballero, J.P. Holgado, V.M. González-delaCruz, S.E. Habas, T. Herranz, M. Salmeron, Chem. Commun., 46 (2010) 1097.
– R. Pereñíguez, V.M. González-DelaCruz, J.P. Holgado, A. Caballero, Appl. Catal.B: 96 (2010) 346.
– V.M. González-Delacruz, F.Ternero, R. Pereñíguez, A. Caballero, J.P. Holgado, Appl. Catal. A: General 384 (2010) 1.
– R. Pereñíguez, J.L. Hueso, J.P. Holgado, F. Gaillard, A. Caballero, Catal. Lett. 131 (2009) 164.
– V.M. Gonzalez-DelaCruz, R.Pereñíguez, F.Ternero, J.P. Holgado, A. Caballero, ACS Catal. 1 (2011) 82.
– Q. Sun, H. Li, J.L. Yan, Z. Yu, X. Yu. Renewable and Sustainable Energy Reviews. 51 (2015) 521-32.
– B. Bharathiraja, T. Sudharsanaa, A. Bharghavi, J. Jayamuthunagai, R. Praveenkumar. Biohydrogen and Biogas. Fuel. 16 (2016) 810-28. 13 de 35
– Y. Gao, J. Jiang, Y. Meng, F. Yan, A. Aihemaiti. Energy Conversion and Management. 171 (2018) 133.
– D.Y. Kalai, K. Stangeland, Y. Jin, W.M. Tucho, Z. Yu. International Journal of Hydrogen Energy. 43 (2018) 19438.
– P. Rosha, S.K. Mohapatra, S.K. Mahla, A, Dhir. Biomass and Bioenergy. 125 (2019) 70.
– B.W. Kwon, J.H. Oh, G.S. Kim, S.P. Yoon, J. Han, S.W. Nam, et al. Applied Energy 227 (2018) 213.
– Y.X. Zeng, L. Wang, C.F. Wu, J.Q Wang, B.X. Shen, X. Tu. Appl. Catal. B: Environm. 224 (2018) 469.
– K. Jabbour, A. Saad, L. Inaty, A. Davidson, P. Massiani, N. El Hassan. Int. J. Hydrogen Energy, 44 (2019) 14889.
– K. Bu, S. Kuboon, J. Deng, H. Li, T. Yan, G. Chen, et al. Appl. Catal B: Environm. 252 (2019) 86-97.
– P.H. Tu, D.N. Le, T.D. Dao, Q.T. Tran, T.C.D. Doan, Y. Shiratori, et al., Int. J. Hydrogen Energy. 45 (2019) 18363.
– H. Arbag. International Journal of Hydrogen Energy. 43 (2018) 6561-74.
– J.J. González-Pérez, J.F. Da Costa-Serra, A. Chica, Int. J. Hydrogen Energy, 45 (2020) 20568-20581.
– J.N.Armor, Appl.Catal.A, 176, 1999, 159.
– D.B.Levin, L.Pitt, M.Love, Int. J. Hydrogen Energy, 29, 2004, 173.
– H.A. Aleksandrov et al., Catal. Sci. Technol. 7, 2017, 3339.
– M. Akri et al., Nature commun. 10, 2019, 5181.
– M. Ryden, P. Ramos, Fuel Procces. Technolg. 96, 2012, 22736.

OBJECTIVES, METHODOLOGY AND WORK PLAN

OBJETIVES:

The main objective of this project is to investigate and develop an integral and innovative approach to produce bioenergy (biomethane and green hydrogen) from low-quality biogenic feedstock produced in a wastewater plant. To achieve this objective is required to achieve the specific objectives of each one of the subprojects. The objectives have the main purpose of valorizing biogas, a renewable raw material derived from biomass to produce alternative biofuels (biomethane and green hydrogen). In this way it is possible to reduce the emission of methane and CO₂.

The fulfillment of these objectives will allow us to improve the capacities of valorization of biogas obtained from disposable wastes. Obtaining green hydrogen through economic procedures is therefore one of the main objectives of the project, which will also result in the reduction of pollutant emissions into the environment.

Figure 5. Diagram of the installation of the laboratory anaerobic digester, with agitation and temperature control, pH and redox potential monitoring, and sludge feeding and sampling systems, and removal, quantification and sampling of the biogas produced

The objectives of the different subprojects participating in the proposal can be summarized as:

Subproject 1:

1. To increase the flow and the quality of biogas produced in the anaerobic digestor of a WWTP (higher CH₄ concentration, lower H₂S content) by codigestion with fruit and vegetable wastes or garden wastes.

2. To identify different sources of fruit and vegetable wastes and selection of the more adequate for codigestion. The study in a microplant the best codigestion parameters

3. To transform biogas into biomethane with low contents H₂S, H₂O, NH₃ and siloxanes.

4. To develop models to study de scaling-up of all processes for their possible implementation at a near WWTP, for scaling up, and studing of the economic and environmental viability of the different processes.

Subproject 2:

1. Design, synthesis, characterization, and optimization of efficient catalysts for the production of syngas by dry-reforming, with low carbon production and/or resistant to coke deposition.

2. Identification of the optimal window of working conditions that allows to improve the catalytic activity, selectivity and stability biogas of dry reforming and bifunctional WGS catalysts.

3. To understand the fundamental reaction mechanisms of dry reforming of biogas, including carbon depositions, catalyst lifetime, and catalyst regeneration conditions for metal-based catalysts.

4. To increase the understanding of the mechanisms and kinetics of catalytic WGS reaction on catalysts containing bifunctional sites (WGS and CO₂ adsorption).

In order to achieve the project objectives, the project has been designed in work packets (WP) with different tasks:

WP1 Design of the codigestion process
1.1. Selection and evaluation of the possible residues for co-digestion and LCA.
1.2. Evaluation of the process and study of process variables over the quality changes in the biogas and biosolids.
WP2 Transformation of biogas into biomethane
2.1. Preparation and characterization of adsorbents.
2.2. Design of the biogas purification process.
WP3: Hydrogen production
3.1. Synthesis, characterization, and optimization of dry reforming catalysts.
3.2. Synthesis, characterization, and optimization of Steam and Bi-reforming catalysts.
3.3. Synthesis, characterization, and optimization of bifunctional WGS catalysts.
3.4. Fundamental study of the reaction mechanism using operando spectroscopy.
3.5. Catalyst optimization.
WP4 Modeling
4.1. Modeling of the anaerobic digestion and codigestion process.
4.2. Modeling of the biomethane production.
4.3. Modeling of the hydrogen production.
WP5 Management and dissemination
5.1. Project management and scientific coordination.
5.2. Dissemination, exploitation, and communication.
5.3. Data management.
5.4. Risk analysis and contingency plan.

Figure 4. Scheme of Raw biogas upgrading

Published Works, Projects, Contracts, Conference Communications

Published Works

1) Autores: L. Ruíz-Rodríguez, A. de Arriba; A. Vidal-Moya; T. Blasco; E. Rodríguez-Castellón; J.M. Lopez Nieto
Título: The role of promoters on the catalytic performance of M_xV₂O₅ bronzes for the selective partial oxidation of H₂S
Ref. revista: Applied Catalysis A: General https://doi.org/10.1016/j.apcata.2022.118900
Clave: Volumen: 647 Páginas, inicial: 118900 final: Fecha: 2022

2) Autores: J.A. Cecilia, E. Vilarrasa-García. N. Chouikhi, R. Morales-Ospino, S. Besghaier, M. Chlendi, M. Bagane, M. Bastos-Neto, D.C.S. Azevedo, E. Rodríguez-Castellón
Título: Activated Carbons synthesized from sucrose using porous clay heterostructures as template for CO₂ adsorption
Ref. revista: Sustainable Chemistry for Climate Action https://doi.org/10.1016/j.scca.2022.100006
Clave: Volumen: 1 Páginas, inicial: 100006 final: Fecha: 2022

3) Autores: I. Barroso-Martín, J. A. Cecilia, E.Vilarrasa-García, D. Ballesteros-Plata, C.P. Jiménez-Gómez, Á. Vílchez-Cózar, A. Infantes-Molina, E. Rodríguez-Castellón
Título: Modification of the textural properties of chitosan to obtain biochars for CO₂-capture processes
Ref. revista: Polymers https://doi.org/10.3390/polym14235240
Clave: Volumen: 14 Páginas, inicial: 5240 final: Fecha: 2022

4) Autores: M.S. Souza, A.J. Martins, J.A.S. Ribeiro, A. Campos, A.C. Oliveira, R.F. Jucá, G.D. Saraiva, M.A.M. Torres, E. Rodríguez-Castellón, R.S. Araujo
Título: Selective Catalytic Reduction of NO_x by CO over Cu(Fe)/SBA-15 Catalysts: Effects of the Metal Loading on the Catalytic Activity
Ref. revista: Catalysts doi.org/10.3390/catal13030527
Clave: Volumen: 13 Páginas, inicial: 527 final: Fecha: 2023

5) Autores: N. Spigariol, L. Liccardo, E. Lushaj, E. Rodríguez-Castellon, I. Barroso Martin, F. Polo, A. Vomiero, E. Cattaruzza, E. Moretti
Título: Titania nanorods array homojunction with sub-stoichiometric TiO₂ for enhanced methylene blue photodegradation
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114134
Clave: Volumen: 119 Páginas, inicial: 114134 final: Fecha: 2023

6) Autores: N. Schiaroli, L. Negahdar, M. Lützen, P.H. Ho, L.J. Allen, A. Natoli, F. Ospitali, F. Maluta, E. Rodríguez-Castellón, C.D. Damsgaard, G. Fornasari, A,M. Beale, P. Benito
Título: Efficient low-loaded ternary Pd-In₂O₃-Al₂O₃ catalysts for methanol production
Ref. revista: Journal of Catalysis https://doi.org/10.1016/j.jcat.2023.05.012
Clave: Volumen: 424 Páginas, inicial: 140 final: 151 Fecha: 2023

7) Autores: D.G. Della Rocca, M. Schneider, F.C. Fraga, A. De Noni Júnior, R.A. Peralta, E. Rodríguez-Aguado, E. Rodríguez-Castellón, R.F.P.M. Moreira
Título: A comprehensive insight into the parameters that influence the synthesis of Ag₂MoO₄ semiconductors via experimental design.
Ref. revista: Journal Materials Science: Materials in Electronics https://doi.org/10.1007/s10854-023-10897-7
Clave: Volumen:34 Páginas, inicial:1500 final: Fecha: 2023

8) Autores:R. de C.F. Bezerra, G.Mota, R.M.B. Vidal, G.D. Saraiva, A.C. Oliveira, A.J.R. Castro, R.S. Araújo, E. Rodríguez-Aguado, J. Jiménez Jiménez, E. Rodríguez-Castellón
Título: Multifunctional properties of alumina-based graphene nanocomposites as catalysts for esters of glycerol production
Ref. revista: Molecular Catalysis https://doi.org/10.1016/j.mcat.2023.113427
Clave: Volumen: 548 Páginas, inicial: 113427 final: Fecha: 2023

9) Autores: A. Raeisi, A. Najafi Chermahini, M. Esmaeilzadeh Khabazi, M. Mohsen Momeni, R. Luque, A. Pineda, E. Rodríguez Castellón, C. Vargas Fernández
Título: Preparation of a novel BiVO₄-Ni(II)/g-C₃N₄ bifunctional photo electrocatalyst for oxidative and absorptive desulfurization of model fuel
Ref. revista: Journal of Alloys and Compounds https://doi.org/10.1016/j.jallcom.2023.172025
Clave: Volumen: 968 Páginas, inicial: 172025 final: Fecha: 2023

10) Autores: L. Hejji, A. Azzouz, L. Pérez-Villarejo, E. Castro, S. Badredine, E. Rodríguez-Castellón
Título: Fe₃O₄@UiO-66-NH₂ based on magnetic solid phase extraction for determination of organic UV filters in environmental water samples
Ref. revista: Chemosphere https://doi.org/10.1016/j.chemosphere.2023.140090
Clave: Volumen: 341 Páginas, inicial: 140090 final: Fecha: 2023

11) Autores: M.E Potter, S. Mediavilla-Madrigal, E. Campbell, L.J Allen, U. Vyas, S. Parry, A. García-Zaragoza, L.M. Martínez-Prieto, P. Oña-Burgos, M. Lützen, C.D Damsgaard, E. Rodríguez-Castellón, N. Schiaroli, G. Fornasari, P. Benito-Martin, A.M. Beale
Título: A High Pressure Operando Spectroscopy Examination of Bimetal Interactions in ‘Metal Efficient’ Palladium/In₂O₃/Al₂O₃ Catalysts for CO₂ hydrogenation
Ref. revista: Angewandte Chemie International Edition https://doi.org/10.1002/anie.202312645
Clave: Volumen: 62 Páginas, inicial: e202312645 final: Fecha: 2023

12) Autores: D.G. Della Rocca, A. De Noni Jr., E. Rodríguez-Aguado, R. Aparecida Peralta, E. Rodríguez-Castellón, G. Li Puma, R.F.P.M. Moreira
Título: Mechanistic insights on the catalytic ozonation of trimethoprim in aqueous phase using geopolymer catalysts produced from mining waste
Ref. revista: Journal of Environmental Chemical Engineering DOI:10.1016/j.jece.2023.111163
Clave: Volumen: 62 Páginas, inicial: 111163 final: Fecha: 2023

13) Autores: J.A. Cecilia, E. Vilarrasa-García, D.C.S. Azevedo, A. Vílchez-Cózar, A. Infantes-Molina, D. Ballesteros-Plata , I. Barroso-Martín, E. RodríguezCastellón
Título: Valorization of wipe wastes for the synthesis of microporous carbons and their application in CO₂ capture, gas separation and H₂-storage.
Ref. revista: Heliyon https://doi.org/10.1016/j.heliyon.2023.e20606
Clave: Volumen: 9 Páginas, inicial: e20606 final: Fecha: 2023

14) Autores: A.J. Martins de Farias, A. da Silva, A. Oliveira, J.V. do Carmo, G. Saraiva, R. Juca, M. Morales, R. Lang, J. Jimenez-Jimenez, E. Rodriguez-Castellon
Título: Catalytic Performances of the Nano FeCo Solids for Biofuel Additives Production: Incorporation of Promoters Effects on the Stability of the Catalysts
Ref. revista: Energy and Fuels https://doi.org/10.1021/acs.energyfuels.3c02881
Clave: Volumen: 37 Páginas, inicial:17328 final:17344 Fecha: 2023

15) Autores: A.F. Crespi, P.N. Zomero, A.L. Pérez, C.D. Brondino, A. Infantes Molina, Y. Garro Linck, G.A. Monti, M.A. Fernández, E. Rodríguez-Castellón, J.M. Lázaro-Martínez.
Título: Montmorillonite materials with paramagnetic metal complexes: structural studies and catalytic degradation of emerging pollutants
Ref. revista: Journal of Environmental of Chemical Engimeering https://doi.org/10.1016/j.jece.2023.111420
Clave: Volumen: 11 Páginas, inicial:111420 final: Fecha: 2023

16) Autores: M. Algueró, L. Zia, R. Jiménez, H. Amorín, I. Bretos, A. Barreto, G.H. Jaffari, E. Rodríguez-Castellón, P. Ramos, M.L. Calzada
Título: Bulk-like ferroelectricity and magnetoelectric response of low-temperature solution-processed BiFeO₃-PbTiO₃ films on Ni for metallic MEMS
Ref. revista: APL Energy https://doi.org/10.1063/5.0172616
Clave: Volumen: 1 Páginas, inicial: 036108 final: Fecha: 2023

17) Autores: D. Tavares Guimarães; L.M. Ramos Mendes; L.B. de Sousa Sabino; E. Sousa de Brito; E. Vilarrasa-García; E. Rodríguez-Castellón; J.A. Cecilia; I.J. da Silva Junior
Título: Partial purification of anthocyanins (Brassica oleracea var. Rubra) from purple cabbage using natural and modified clays as adsorbent
Ref. revista: Adsorption Science and Technology https://doi.org/10.1155/2023/2724122
Clave: Volumen: 2023 Páginas, inicial: 2724122 final: Fecha: 2023

18) Autores: A. Misol, I. Giarnieri, F. Ospitali, A. Ballarini, J. Jiménez-Jiménez, E. Rodríguez-Castellón, V. Rives, F. Martín Labajos, G. Fornasari, P. Benito
Título: CO₂ hydrogenation over Ru hydrotalcite-derived catalysts
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114362
Clave: Volumen: 425 Páginas, inicial: 114362 final: Fecha: 2024

19) Autores: P.A.S. Moura, E.D.S. Ferracine, E. Rodríguez-Aguado, D.A.S. Maia, D.C. Melo, S. Valencia, D. Cardoso, F. Rey, M. Bastos-Neto, E. Rodríguez-Castellón, D. C. S. Azevedo
Título: Assessment of the stability of LTA zeolites under natural gas drying TSA conditions
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2023.114410
Clave: Volumen: 427 Páginas, inicial:114410 final: Fecha: 2024

20) Autores: M.R. Oliveira, Y. Teles Barbosa, T.S. Lima Da Silva, J.A. Cecilia , E. Rodríguez-Castellón, S.M. Egues, J.F. De Conto
Título: One-pot synthesis and surfactant removal from MCM-41 by microwave irradiation
Ref. revista: Molecules https://doi.org/10.3390/molecules29020460
Clave: Volumen: 29 Páginas, inicial: 460 final: Fecha: 2024

21) Autores: M. Schneider, E. Rodríguez-Castellón, M.O. Guerrero-Pérez, D. Hotza, A. De Noni Junior, R.F.P.M. Moreira
Título: Advances in Electrospun Composite Polymer/Zeolite and Geopolymer Nanofibers: A Comprehensive Review
Ref. revista: Separation and Purification Technologies https://doi.org/10.1016/j.seppur.2024.126684
Clave: Volumen: 340 Páginas, inicial: 126684 final: Fecha: 2024

22) Autores: C. Galdeano-Ruano; S. Gutiérrez-Tarriño; C.W. Lopes; J. Mazarío; L.E. Chinchilla; G. Agostini; J.J. Calvino; J.P. Holgado; E. Rodríguez-Castellón; A. Roldán; P. Oña-Burgos
Título: Developing and Understanding Leaching-Resistant Cobalt Nanoparticles via N/P Incorporation for Liquid Phase Hydroformylation
Ref. revista: Journal of Catalysis https://doi.org/10.1016/j.jcat.2024.115374
Clave: Volumen: 431 Páginas, inicial: 115374 final: Fecha: 2024

23) Autores: D.A.S. Maia, T.M. Azevedo, D.S. Pereira, R.A.M. Castro, B.O. Nascimento, E. Rodríguez-Castellón, M. Bastos-Neto, D.C.S. Azevedo
Título: Water vapor adsorption on small pore ion-exchanged zeolites
Ref. revista: Adsorption https://doi.org/10.1007/s10450-024-00442-1
Clave: Volumen: on line Páginas, inicial: final: Fecha: 2024

24) Autores: D.G. Domínguez-Talamantes, D. Vargas-Hernández, J.T. Hernández-Oloño, E. Rodríguez-Castellón, M. Arellano-Cortaza, S.J. Castillo, J.C. Tánori-Córdova
Título: Enhanced photocatalytic activity of FeSO₄ in a ZnO photocatalyst with H₂O₂ for dye degradation
Ref. revista: Optik https://doi.org/10.1016/j.ijleo.2024.171753
Clave: Volumen: 304 Páginas, inicial: 171753 final: Fecha: 2024

25) Autores: D.A. Valdivieso-Vera, G.A. Flores-Escamilla, J.J. Cano-Gómez, I. Barroso-Martín, E. Rodríguez-Castellón, I.A. Santos-López, M.O. Guerrero-Pérez
Título: Effect of Nb as dopant of hydrotalcite catalysts during the ethanol condensation to optimize n-Butanol production
Ref. revista: Catalysis Today https://doi.org/10.1016/j.cattod.2024.114658
Clave: Volumen: 433 Páginas, inicial:114658 final: Fecha: 2024

26) Autores: F. Zorzetto, D. Ballesteros-Plata, A. Perosa, E. Rodríguez-Castellón, M. Selva, D. Rodríguez-Padrón
Título: Orthogonal assisted tandem reactions for the upgrading of bio-based aromatic alcohols using chitin derived mono and bimetallic catalysts
Ref. revista: Green Chemistry https://doi.org/10.1039/D3GC04848A
Clave: Volumen: On line Páginas, inicial: final: Fecha: 2024

27) Autores: P. Jabbari, A.N. Chermahini, R. Luque , A. Pineda , E.Rodríguez Castellón
Título: Synthesis of Cu-doped TiO₂ modified BiVO₄ for photocatalytic oxidative desulfurization (PODS) of a model fuel
Ref. revista: Journal of Photochemistry & Photobiology, A: Chemistry https://doi.org/10.1016/j.jphotochem.2024.115625
Clave: Volumen: 452 Páginas, inicial: 115625 final: Fecha: 2024

28) Autores: G. Mota Bertoldo, A.C. Oliveira, G. Dantas Saraiva, R. Jucá, J. Gadelha da Silva Filho, E. Rodríguez-Aguado, J. Jiménez-Jiménez, E. Rodríguez-Castellón
Título: Metal-doped niobate pyrochlores and double-perovskites for glycerol valorization: Structural and electronic properties and DFT calculations
Ref. revista: Dalton Transactions https://doi.org/10.1039/D4DT00898G

Clave: Volumen: Aceptado Páginas, inicial: final: Fecha: 2024

29) Autores: H. Bernardo Jorge, D. Della Rocca, E. Herrera, E. Rodríguez-Castellón, A. Gil. S. Amorim, J.P. Winiarski, I. da Cruz Vieira, R.M. Moreira, M. Algarra, R. Peralta.
Título: A sustainable approach for the valorization of lignocellulosic biomass in active photo- and electrocatalyst carbon dots
Ref. revista: Waste and Biomass Valorization https://doi.org/10.1007/s12649-024-02610-4
Clave: Volumen: On line Páginas, inicial: final: Fecha: 2024

30) Autores: F.J. Soares Barros, R. Moreno Tost, J.A. Cecilia, F.M.T. de Luna, E. RodríguezCastellón R. Silveira Vieira
Título: Unveiling the Catalytic Potential of K2ZnF6 fluoroperovskite for Glycerol Oligomerization,
Ref. revista: Biomass Conversion and Biorefinery http://doi.org/10.1002/bbb.2660
Clave: Volumen: on line Páginas, inicial: final: Fecha: 2024

31) Autores: P.J..Morais Lima, N. Saravia Rios, E. Vilarrasa-García, E. Rodríguez-Castellón, J.A. Cecilia, L.R.B. Gonçalves
Título: Preparation of a heterogeneous biocatalyst through Thermomyces lanuginosus lipase immobilization on pore-expanded SBA-15
Ref. revista: International Journal of Biological Macromolecules https://doi.org/10.1016/j.ijbiomac.2024.133359
Clave: Volumen: 274 Página, inicial:133359 final: Fecha: 2024

32) Autores: D. Polidoro, T. Chhabra, E. Rodríguez-Castellón, A. Perosa, R. Luque, D. Rodriguez-Padron, M. Selva
Título: Pd-N-Doped Carbons for Chemoselective Hydrogenation of Cinnamaldehyde: Unravelling the Influence of Particle Size and Support in Multiphase Batch and Continuous-Flow Systems
Ref. revista: Applied Catalysis A: General https://doi.org/10.1016/j.apcata.2024.119864
Clave: Volumen: 685 Página, inicial:119864 final: Fecha: 2024

33)Autores: M. Esmaeilzadeh Khabazi, A. Najafi Chermahini, R. Luque, A. Pineda, E. Rodriguez-Castellon, C. Vargas Fernández.
Título: Hydrogenation of ethyl levulinate to gamma-valerolactone with formic acid and a palladium-manganese catalyst immobilized on dendritic fibrous nano-silica (DFNS)
Ref. revista: Energy & Fuels https://doi.org/10.1021/acs.energyfuels.4c02462
Clave: Volumen: 38 line Página, inicial: 14387 final:14401 Fecha: 2024

34) Autores: D.A. Valdivieso-Vera; I. Alonso Santos-López; J.J. Cano-Gómez; G.A. Flores-Escamilla; J. Rivera de la Rosa; E. Rodríguez-Castellón; I. Barroso-Martín; M.O. Guerrero-Pérez
Título: Copper-supported hydroxyapatite catalysts for bio-isobutanol synthesis from sustainable short-chain alcohols
Ref. revista: Applied Catalysis A: General https://doi.org/10.1016/j.apcata.2024.119881
Clave: Volumen: 685 Página, inicial: 119881 final: Fecha: 2024

35) Autores: M. Selva, C. Bersani, D. Rodríguez-Padrón, D. Ballesteros, E. Rodríguez-Castellón, A. Perosa
Título: Selective Multiphase-Assisted Oxidation of Bio-Sourced Primary Alcohols over Ru- and Mo-Carbon Supported Catalysts
Ref. revista: ChemSusChem https://doi.org/10.1002/cssc.202400888
Clave: Volumen: On line Página, inicial: final: Fecha: 2024

36) Autores: J.V.C. Carmo, J. Nogueira, G. M. Bertoldo, F.E. Clemente, A.C. Oliveira, A.F. Campos, G.C.S. Duarte, S. Tehuacanero-Cuapa, J. Jiménez-Jiménez, E. Rodríguez-Castellón
Título: Porous Nanostructured Catalysts Based on Silicates and their Surface Functionality: on the Effects of Silica Source and Metal added in Glycerol Valorization
Ref. Revista: Catalysts https://doi.org/10.3390/catal14080526
Clave: Volumen: 14 Página, inicial: 526 final: Fecha: 2024

37) Autores: O. Trentin, D. Ballesteros-Plata, E. Rodríguez-Castellón, L. Puppulin, Maurizio Selva, A. Perosa, D. Rodríguez- Padrón
Título: Upcycling of chitin to cross-coupling catalysts: Tailores supports and opportunities in mechanochemistry
Ref. Revista: ChemSusChem https://doi.org/10.1002/cssc.202401255
Clave: Volumen: On line Página, inicial: final: Fecha: 2024

38) Autores: B. Shani, L. Liccardo, M. Bordin, I. Barroso Martín , A. Infantes-Molina, E. Rodríguez-Castellón, K.B. Ibrahim, A. Vomiero, E. Moretti
Título: Ce^3+/4+–TiO₂ nano-octahedra as active photocatalysts for ciprofloxacin photodegradation under solar light
Ref. Revista: Advanced Sustainable System
Clave: Volumen: On line Página, inicial: final: Fecha: 2024

39) Autores: D.F. Almeida, R.C. Santos, Y.L Lam, J.M.M. Ferreira, E. Rodríguez-Castellón , D. Ballesteros-Plata, J.M. Lázaro-Martínez, A. Martínez, M. A. Arribas, L.A.M. Pontes
Título: Desulfurization reactions of Thiophene and Cyclohexane over Zn and Nb Modified Zeolites in FCC Process
Ref. Revista: Catalysis Today https://doi.org/10.1016/j.cattod.2024.115009
Clave: Volumen: On line Página, inicial: final: Fecha: 2024

Works related to TED but without thanks

1) Autores: D. Ballesteros-Plata, A. Infantes-Molina, E. Rodríguez-Castellón, M. A. Cauqui, M. P. Yeste Sigüenza
Título: Improving noble metal catalytic activity in the dry reforming of Methane by adding niobium
Ref. revista: Fuel https://doi.org/10.1016/j.fuel.2021.121996
Clave: Volumen: 308 Páginas, inicial: 121996 final: Fecha: 2022

2) Autores: R.G. Santiago, J.A. Coelho, S.M.P. de Lucena, A.P.S. Musse, M. de F. Portilho, E. Rodriguez-Castellón, D.C.S. de Azevedo, M. Bastos-Neto
Título: Synthesis of MeOH and DME from CO₂ hydrogenation over commercial and modified catalysts
Ref. revista: Frontiers doi:10.3389/fchem.2022.903053
Clave: Volumen: 10 Páginas, inicial:903052 final: Fecha: 2022

3) Autores: R. Ojeda-Lopez, E. Vilarrasa-García, D.C.S. Azevedo, C. Felipe, J.A. Cecilia, E. Rodríguez-Castellon
Título: CO₂ selectivity in CO₂:CH₄ and CO₂:N₂ mixtures on carbon microfibers (CMFs) and carbon microspheres (CMSs)
Ref. revista: Fuel https://doi.org/10.1016/j.fuel.2022.124242
Clave: Volumen: 324 Páginas, inicial: 124242 final: Fecha: 2022

4) Autores: J. Nascimento, R.C. Bezerra, E. Assaf, A. Lucrecio, R. Araujo, G. Saraiva, E. Rodriguez-Castellon, E. Rodriguez Aguado, G. Pinheiro, A. Oliveira.
Título: Investigation of the deactivation behavior of MeMo/La₂O₃-Al₂O₃ and MeMo/Nb₂O₅ supported catalysts (Me=Pt, Ni and Co) in tri-reforming of methane
Ref. revista: Energy and Fuels https://doi.org/10.1021/acs.energyfuels.2c03120
Clave: Volumen:37 Páginas, inicial:3836 final:3853 Fecha: 2023

5) Autores: N. Schiaroli, L. Negahdar, M. Lützen, P.H. Ho, L.J. Allen, A. Natoli, F. Ospitali, F. Maluta, E. Rodríguez-Castellón, C.D. Damsgaard, G. Fornasari, A,M. Beale, P. Benito
Título: Efficient low-loaded ternary Pd-In₂O₃-Al₂O₃ catalysts for methanol production
Ref. revista: Journal of Catalysis https://doi.org/10.1016/j.jcat.2023.05.012
Clave: Volumen: 424 Páginas, inicial: 140 final: 151 Fecha: 2023

Related projects

Título del proyecto: One REactor concept for hydrogeN storage and generation with LOHC
Entidad financiadora: RHyO cluster, Hydrogen Research in Occitania (Francia)
Entidades participantes: Institut Charles Gerhardt Montpellier (ICGM),Universidad de Montpellier 2 (Francia) y Universidad de Málaga
Duración, desde 01/09/2023 al 31/08/2024 Cuantía de la subvención: 80000,00 €
Investigador principal: Mélanie Taillades y Enrique Rodríguez Castellón
Número de investigadores participantes: 6

Título del proyecto: H₂Excellence: Fuel Cells and Green Hydrogen Centers of Vocational Excellence towards affordable, secure, and sustainable energy for Europe
Entidad financiadora: ERASMUS-EDU-2022-PEX-COVE, propuesta: 101104447
Entidades participantes: Universidad de Málaga y 23 centros europeos
Duración, desde 01/04/2023 al 31/03/2025 Cuantía de la subvención: 112214 €
Investigador principal: María Olga Guerrero Pérez y Enrique Rodríguez Castellón
Número de investigadores participantes: 2

Título del proyecto: CAPICUA (Bio/photo)Catalysis, Adsorption and Process Intensification to Advance CO₂ Capture and Utilization
Entidad financiadora: el Consejo Nacional de Desarrollo Científico y Tecnológico, CNPq/MCT (Brasil) 406710/2022
Entidades participantes: Universidad Federal de Ceará (Brasil), Universidad de Málaga
Duración, desde 22/12/2022 al 31/12/2027 Cuantía de la subvención: €
Investigador principal: Diana Cristina Azevedo
Número de investigadores participantes:

Título del proyecto: Sustainable H₂ production, purification and storage
Entidad financiadora: el Consejo Nacional de Desarrollo Científico y Tecnológico, CNPq/MCT (Brasil) 408071/2022-2
Entidades participantes: Universidad Federal de Ceará (Brasil), Universidad de Málaga
Duración, desde 01/12/2022 al 30/11/2024 Cuantía de la subvención: €
Investigador principal: Diana Cristina Azevedo
Número de investigadores participantes:

Invitation to submit full proposal
The Clean Energy Transition Partnership (CETPartnership) thanks you for your pre-proposal, Cetp2023-00060, BioThermix, “Bioenergy-driven thermoelectric co-generation for carbon-negative power systems” submitted under the CETPartnership Joint Call 2023, TRI2 – CM2023-03A (ROA) Advanced renewable energy (RE) technologies for power production. We are pleased to inform you that your pre-proposal is invited to submit a full proposal.
Proyecto sometido con la Universidad de Aveiro, Universidad Complutense de Madrid y CNRS

Contracts with companies

Proyecto sometido con la Universidad de Aveiro, Universidad Complutense de Madrid y CNRS

Título del contrato/proyecto: Convenio de colaboración entre el Consorci D’aigüesde Tarragona y la Universidad de Málaga para la realización de un proyecto sobre producción industrial de adsorbentes mediante la utilización de fangos de la ETAP de L’Ampolla
Tipo de contrato: Investigación y Desarrollo Tecnológico
Empresa/Administración financiadora:
Entidades participantes: Depto. Química Inorgánica (Univ. Málaga), Depto. Ingeniería Química (UMA)
Duración, desde: 26/04/2023 hasta: 25/04/2024
Investigador responsable: José Jiménez Jiménez
Número de investigadores participantes: 4
PRECIO TOTAL DEL PROYECTO:

Conference communications

Autores: E. Rodríguez Castellón
Título: Carbon dioxide capture and valorization with new adsorbents and catalysts
Congreso: I Workshop Nacional INCT CAPICUA
Comunicación: Conferencia Plenaria
Publicación: web
Lugar de celebración: Fortaleza, Brasil Fecha: 2024

Autores: M.R. Oliveira, E. Rodríguez-Castellón, S.M. Egues, J.F. De Conto,
Título: Microwave synthesis MCM-41 and its application in CO₂ capture
Congreso: 11th World Congress of Chemical Engineering
Comunicación: póster
Publicación: Book of abstracts
Lugar de celebración: Buenos Aires Fecha: 2023

Autores: M. Schneider, R.F.M.P. Moreira, A. De Noni Jr.,D. Hotza, M. Calzado, O. Guerrero-Pérez, E. Rodríguez Castellón
Título: Zeolite/Geopolymer composites with hierarchical porosity manufacture by 3D printing for applications in CO₂ capture
Congreso: 9th Czech-Italian-Spanish Conference On Molcular Sieves and Catalysis
Comunicación: Oral
Publicación: Book of abstracts
Lugar de celebración: Toledo Fecha: 2023

Autores: Enrique Rodríguez-Castellón
Título: Adsorption, Catalysis and Technology Transfer
Congreso: 14th Encontró Brasileiro sobre Adsorçao
Comunicación: Plenaria
Publicación: Book of Abstarct on line
Lugar de celebración: Brasilia (Brasil) Fecha: 2022

Autores: Enrique Rodríguez-Castellón
Título: Low Cost Adsobents
Congreso: International Panel “Perspectives and Challenges in CO₂ capture by Adsorption
Comunicación: Plenaria
Publicación: Youtube
Lugar de celebración: Fortaleza (Brasil) Fecha: 2022

Autores: Enrique Rodríguez-Castellón
Título: Química Inorgánica e Transferencia de Tecnología
Congreso: V WORKSHOP DE QUÍMICA INORGÁNICA
Comunicación: Plenaria
Publicación: Book of Abstarct
Lugar de celebración: Manaos (Brasil) Fecha: 2022

Autores: J.A. Cecilia, E. Vilarrasa-García, A. Vilchez-Cózar, A. Infantes-Molina, D. Ballesteros-Plata, I. Barroso-Martín, E. Rodríguez-Castellón
Título: Valorization of wipe waste for the synthesis of microporous carbons and their application in CO₂ capture
Congreso: XXX International Materials Research Congress
Comunicación: Oral
Publicación: web page
Lugar de celebración: Cancún (México) Fecha: 2022

Autores: M.R. Oliveira, J.A. Cecília, P.F. Nuñez Coello, E. Rodriguez-Castellón
Título: Síntesis por microondas de zeólita a base de caolinita: Adsorción de CO₂
Congreso: 42 Reunión Ibérica de Adsorción
Comunicación: Oral
Publicación: Libro de abstarct
Lugar de celebración: Valencia Fecha: 2022

Autores: M.R. Oliveira, J.F. De Conto, S.M. Egues, E.Rodríguez Castellón
Título: CO₂ adsorption capacities of MCM-41 silica synthesized by microvawe irradiation and functionalized with PEI
Congreso:20th International Zeolite Conference 2022
Comunicación: Póster
Publicación: www.izc2022.com ISBN: 978-84-09-42100-8
Lugar de celebración: Valencia Fecha: 2022

Autores: P.A.S. Moura, D.C. Melo , E. Rodríguez-Aguado, D.A.S. Maia, R. Singh, P. A. Webley, M. Bastos-Neto, E. Rodríguez-Castellón , D.C.S. Azevedo
Título: Hydrothermal stability of chabazite applied in temperature swing adsorption process
Congreso:20th International Zeolite Conference 2022
Comunicación: Póster
Publicación: www.izc2022.com ISBN: 978-84-09-42100-8
Lugar de celebración: Valencia Fecha: 2022

Published Works

List of works published in scientific journals.

View full list

Conference Communications

Participations in conferences.

View full list

Nothing Found

Sorry, no posts matched your criteria

SOCIAL AND ECONOMIC IMPACT
WWTP2GREENFUELS

SOCIAL AND ECONOMIC IMPACT

socio-economic IMPACT

The present project is in line with the European target of low-carbon Energy, and contribute to the UN sustainability goals Affordable and clean energy, Decent work and economic growth, Industrial, innovation and infrastructure, sustainable cities and communities, Sustainable consumption and production and Climate changes.

In particular, one of the goals of the project is increase the production of biogas and reduce the level of impurities contributing to the deployment of improved bioenergy technologies. The implementation of co-digestion process during anaerobic fermentation followed by biogas upgrading eliminating contaminants such as H₂S, NH₃ are key aspects in this project.

The co-digestion of FVWs and/or garden residues together with the mixed sludge of the WWTP will represent very important benefits not only for the municipal WWTP, but also will mitigate the important environmental problems associated with these organic residues reaching the municipal landfill, while creating good-quality jobs in the region. Also, this technology could be implemented in many other facilities with similar conditions throughout the Mediterranean and many other places around the world. The by-products (digestate production) quantity and quality will also improve, promoting opportunities for a circular economy of nutrients such as P (within the EU list of critical raw materials). This will also allow the WWTP to provide a comprehensive management of local residues.

The disposal of high quality biogas is of great interest in the energetic sector, reducing the dependence of fossil fuels, and preserving the existing infrastructure, storage facilities, compressor and pipelines, with an important economic benefit. In addition, in a second part of the project, biogas upgrading to produce green hydrogen of high purity will be considered. The final idea of the WWTP is to supply hydrogen to a future hydrogen station for its own consume, or even used for transport vehicles of the municipalities. This will raise Spain a point on the supplier scale of biomethane and Hydrogen, and will contribute to a secure energy supply and job creation.

This project could be the starting point to generate a larger project with consortia at regional, national and European level, but especially, could be a long-term stable employment generator, which not only helps the protection of the environment, but also to the development of poor countries.

As social interest, this project will show the potential of bioenergy to contribute to a sustainable environment, based on material recycling, zero-net CO₂ emission, and resource sufficiency.

As a summary, the present project aims to bring together the following socio-economic benefits:

Simple, robust and flexible digestion technology

The utilisation of non-conventional biomass wastes by using the simple, robust and flexible digestion technology that allows to exploit feedstock having high humidity and/or ash content, otherwise left to decompose naturally producing CH₄ (very harmful greenhouse gas) or openly burned or converted with low efficiency and high environmental impacts. This will give the opportunity to waste water treatment plant (WWTP) to have economic advantages 32 de 35 of selling their wastes to produce biomethane or hydrogen or realising their plant for internal use.

new market for anaerobic digestion and reforming process manufacturers

The technologies of generation of biomethane and green hydrogen proposed in the project will open a new market for anaerobic digestion and reforming process manufacturers giving the opportunity to increase efficiency and reduce emissions and to the chemical manufacturers to enter the biomass from WWTP and energy market.

Lower greenhouse gas emissions

The use of WWTP to offset the use of fossil fuels can lower greenhouse gas emissions. The mitigation of atmospheric greenhouse gases has a beneficial effect on the climate change, water quality, human health and in decoupling economic growth from environmental degradation.

Promote H2 production from biogas

Accelerate the deployment of bioenergy technologies. Promote H2 production from biogas from anaerobic digester of WWTP.

Contact us

Get in Touch

If you have any questions or would like

to contact us for another reason,

write us an email to am0236@uma.es

or fill out the contact form.

Thank you!

CONFERENCIA

A Panorama of Recent Research and Developments in CO2 Capture and Conversion

Dr. Moisés Bastos Neto

An integral approach for the production of bioenergy (biomethane and green hydrogen) from wastewater treatment plants as part of a sustainable energetic transition

WWTP2GREENFUELS PROPOSAL

WWTP2 GREENFUELS PROPOSAL

The main objective of this project is

Sinergetic skills of the groups and subprojects

Biomethane and Hydrogen Production and Purification from an Anaerobic Digester.

CO2, H2S and NH3 capture

Gas separation

Surface Analysis

Adsorbents preparation

Codigestion

Multiphysics Modeling

Innovative Catalytic Formulations for Dry Reforming and WGS Reactions and their Impact in the Sustainable Production of Green Hydrogen from Biogas

Thermocatalytic valorization of CO2

Thermocatalytic ODH of ethane and CO2

Hydroformilation of olefins with CO2

Operando characterization

In-situ tests

OUR TEAM

State-of-the-art of Green biomethane and hydrogen production

OBJECTIVES, METHODOLOGY AND WORK PLAN

OBJETIVES:

The objectives of the different subprojects participating in the proposal can be summarized as:

In order to achieve the project objectives, the project has been designed in work packets (WP) with different tasks:

Published Works, Projects, Contracts, Conference Communications

Published Works

Conference Communications

SOCIAL AND ECONOMIC IMPACT

SOCIAL AND ECONOMIC IMPACT

socio-economic IMPACT

As a summary, the present project aims to bring together the following socio-economic benefits:

Simple, robust and flexible digestion technology

new market for anaerobic digestion and reforming process manufacturers

Lower greenhouse gas emissions

Promote H2 production from biogas

Contact us

Get in Touch

CONTACT

A Panorama of Recent Research and Developments in CO₂ Capture and Conversion

Biomethane and Hydrogen
Production and Purification from
an Anaerobic Digester.

CO₂, H₂S and NH₃ capture

Thermocatalytic valorization of CO₂

Thermocatalytic ODH of ethane and CO₂

Hydroformilation of olefins with CO₂